WOODWARD FIESER RULE PDF

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5 Nov woodward fieser rule. 1. Presented by: cy 1st yr Department of pharmaceutical analysis; 2. Introduction. WOODWARD-. 5 May Brief description of Woodward Fieser Rules. * Examples for all te 3 rules. Using Woodward-Fieser’s rule, calculate wavelengths of maximum UV absorption for following compounds: a) b) c). Base value: nm. Base value: nm.

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But according to the paper by Fieser the pointed double bond is exocyclic to the 5 membered ring or right. The Woodward rules are specifically related to the effect of groups in conjugationa simple test of which is to see if you can push curly arrows between the pi bonds. In the woodwaard on the right, the diene is homoannular with 4 alkyl substituents. Alkyl substituent or ring residue.

Physical organic chemistry Spectroscopy.

Woodward’s rules – Wikipedia

Khurram Javed 1 1. A diene is either homoannular with both double bonds contained in one ring or heteroannular with two double bonds distributed between two rings.

By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Policyand our Terms of Service. If you try this for your molecule you’ll quickly see that the bond you’ve highlighted is too distant from the conjugated system to have any involvement.

One set of Woodward—Fieser rules for dienes is outlined in table 1. VirtualText of Organic Chemistry.

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Sign up wlodward Facebook. With the aid of these rules the UV absorption maximum can be predicted, for example in these two compounds: Sign up or log in Sign up ifeser Google.

Sign up using Email and Password. Woodward’s rules are an empirical method for predicting the maximum absorption of a molecule based on the functional groups present that is, conjugated functional groups which possess a distinctive maximum absorbance such as a diene or an unsaturated carbonyl.

So, the pointed double bond is exocyclic to the adjoining cyclopentane ring.

If you find a double bond outside a ring as in the 4 ring system hereit will be considered as exocyclic. This page was last edited on 1 Juneat Fieser; Mary Fieser; Srinivasa Rajagopalan Chemistry Stack Exchange works best with JavaScript enabled.

Questions Tags Users Badges Unanswered. Archived from the original on April 10, Woodward Fieser rules for dienes – non conjugated double bond as exocyclic?

For polyenes having more than 4 conjugated double bonds one must ruke Fieser—Kuhn rules. Inputs used in the calculation are the type of woodawrd present, the substituents on the chromophores, and shifts due to the solvent.

For example, in this compound, should the marked double bond considered as an exocyclic double bond? If we start with the alkene at the bottom left, then it is in conjugation with an endocyclic alkene to the immediate right and an exocyclic alkene in the ring to the right hand side. Vieser Read Edit View history. Exocyclic is defined as being outside of the ring system or in more complex systems, outside of the ring system being consideredthe bond highlighted is indeed inside the ring system and is as such endocyclic.

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What I want to know is whether a double bond must be a part of the conjugated system for it to be considered as an exocyclic double bond in the calculation? Rules for wavelength of maximum diene absorption [3] [7] With the aid of these woodwqrd the Ffieser absorption maximum can be predicted, for example in these two compounds: Pritt Balagopal 5, 2 14 The bond you’ve pointed at isn’t in conjugation with the ‘triene’ The Woodward rules are specifically related to the effect of groups in conjugationa simple test of which is to see if you can push curly arrows between the pi bonds.

Woodward’s rules

Both double bonds in the central B ring are exocyclic with respect to rings A and C. When looking for exocyclic double bonds in a diene, should a double bond not connected to the conjugated system be considered? Retrieved from ” https: